{"id":2506,"date":"2022-10-27T15:16:00","date_gmt":"2022-10-27T15:16:00","guid":{"rendered":"http:\/\/www.gongyeqx.com\/?p=2506"},"modified":"2022-09-05T15:16:57","modified_gmt":"2022-09-05T07:16:57","slug":"%e3%80%90%e7%83%ad%e5%88%86%e6%9e%90%e8%af%be%e5%a0%82%e3%80%91%e5%88%a9%e7%94%a8topem%e6%8a%80%e6%9c%af%e5%88%86%e7%a6%bb%e6%98%be%e7%83%ad%e6%b5%81%e5%92%8c%e6%bd%9c%e7%83%ad%e6%b5%81","status":"publish","type":"post","link":"http:\/\/www.gongyeqx.com\/?p=2506","title":{"rendered":"\u3010\u70ed\u5206\u6790\u8bfe\u5802\u3011\u5229\u7528TOPEM®\u6280\u672f\u5206\u79bb\u663e\u70ed\u6d41\u548c\u6f5c\u70ed\u6d41"},"content":{"rendered":"
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\u6839\u636e\u516c\u5f0f\uff08<\/span>2\uff09\u5f53\u9891\u7387\u63a5\u8fd1<\/span>0\u65f6\u5019\uff0c\u7c7b\u4f3c\u4e8e\u51c6\u7a33\u6001\uff0c\u6b64\u65f6\u53ef\u9006\u70ed\u6d41\u4e0e\u663e\u70ed\u57fa\u672c\u5bf9\u5e94\uff0c\u4e0d\u53ef\u9006\u70ed\u6d41\u4e0e\u6f5c\u70ed\u6d41\u57fa\u672c\u5bf9\u5e94\uff1b\u5f53\u9891\u7387\u65e0\u7a77\u5927\u65f6\u5019\uff0c\u5177\u6709\u9891\u7387\u4f9d\u8d56\u7684\u6bd4\u70ed\u5bb9\u53d8\u5316\u5b8c\u5168\u4f9d\u8d56\u52a8\u529b\u5b66\u8fc7\u7a0b\uff0c\u8fd9\u90e8\u5206\u4f53\u73b0\u5728\u4e0d\u53ef\u9006\u70ed\u6d41\u66f2\u7ebf\u4e0a\u3002\u5728\u67d0\u4e2a\u7279\u5b9a\u9891\u7387\u4e0b\u7684\u8c03\u5236\u4fe1\u53f7\u5219\u53ef\u9006\u4e0e\u4e0d\u53ef\u9006\u70ed\u6d41\u4ecb\u4e8e\u4e24\u8005\u4e4b\u95f4\u3002<\/span>ADSC\u4e2d\u53ef\u9006\u70ed\u6d41\u66f2\u7ebf\u662f\u5bf9\u5e94\u52a0\u70ed\u901f\u7387\u65e0\u6ede\u540e\u7684\u70ed\u6d41\u90e8\u5206\uff0c\u4e0d\u53ef\u9006\u70ed\u6d41\u5219\u4e3a\u603b\u70ed\u6d41\u51cf\u6389\u53ef\u9006\u70ed\u6d41\u5f97\u5230\u3002<\/span><\/span><\/p>\n <\/span><\/p>\n <\/span><\/p>\n \u7136\u800c\uff0c\u7531\u4e8e\u5305\u62ec\u6b63\u5f26\u6e29\u5ea6\u8c03\u5236<\/span>ADSC\u5728\u5185\u7684\u5355\u9891\u5e38\u89c4<\/span>TMDSC\u53d7\u5b9e\u9a8c\u6761\u4ef6\u9650\u5236\uff0c\u6d4b\u7684\u6570\u636e\u53ef\u80fd\u663e\u8457\u504f\u79bb\u663e\u70ed\u6d41\u548c\u6f5c\u70ed\u6d41\u8fd9\u4e24\u4e2a\u70ed\u6d41\u5206\u91cf\u3002\u7279\u522b\u662f\u56e0\u4e3a\u4e0d\u53ef\u9006\u70ed\u6d41\u7684\u9891\u7387\u4f9d\u8d56\u6027\uff0c\u5982\u679c\u52a8\u6001\u6d4b\u91cf\u53ef\u9006\u70ed\u6d41\uff0c\u901a\u5e38\u4f1a\u6bd4\u663e\u70ed\u6d41\u5c0f\uff0c\u56e0\u4e3a\u6240\u6709\u8017\u65f6\u957f\u4e8e\u7279\u5f81\u6d4b\u91cf\u65f6\u95f4<\/span>(\u4f8b\u5982<\/span>60\u79d2<\/span>)\u7684\u65f6\u95f4\u4f9d\u8d56\u6027\u8fc7\u7a0b\u90fd\u4e0d\u4f1a\u88ab\u6d4b\u91cf\uff0c\u6240\u4ee5\u7528\u76f8\u5173\u8ba1\u7b97\u7a0b\u5e8f\u5f97\u5230\u7684\u53ef\u9006\u70ed\u6d41\u548c\u4e0d\u53ef\u9006\u70ed\u6d41\u5206\u91cf\u4e0d\u80fd\u6309\u7167\u70ed\u529b\u5b66\u6765\u5206\u6790\u3002\u8fd9\u4e5f\u662f\u5c06\u88ab\u5206\u79bb\u7684\u70ed\u6d41\u6210\u5206\u79f0\u4e3a\u53ef\u9006\u548c\u4e0d\u53ef\u9006\u70ed\u6d41\uff08\u800c\u4e0d\u662f\u76f4\u63a5\u79f0\u4e3a\u663e\u70ed\u6d41\u548c\u6f5c\u70ed\u6d41\uff09\u7684\u539f\u56e0\u3002\u5728\u51c6\u9759\u6001\u6d4b\u91cf\u4e2d\uff0c\u663e\u70ed\u548c\u53ef\u9006\u70ed\u6d41\u4e4b\u95f4\u7684\u5dee\u522b\u53d8\u5f97\u5f88\u5c0f\uff0c\u53ef\u4ee5\u5c06\u4e24\u8005\u5bf9\u5e94\uff0c\u80fd\u591f\u7406\u60f3\u5730\u5206\u79bb\u663e\u70ed\u6d41\u548c\u6f5c\u70ed\u6d41\u3002<\/span><\/span><\/p>\n <\/span><\/p>\n \u591a\u9891\u968f\u673a\u6e29\u5ea6\u8c03\u5236<\/span>TOPEM\u6280\u672f<\/span><\/span><\/strong><\/p>\n <\/span><\/p>\n TOPEM®\u662f\u4e00\u79cd\u591a\u9891\u6e29\u5ea6\u8c03\u5236<\/span>DSC\u6280\u672f\uff0c\u5b83\u4e0e\u4f20\u7edf\u7684\u6e29\u5ea6\u8c03\u5236\u6280\u672f\u7684\u4e0d\u540c\u5728\u4e8e\u8c03\u5236\u51fd\u6570\u7684\u7c7b\u578b\u548c\u5206\u6790\u5904\u7406\u7684\u65b9\u6cd5\u3002\u5176\u6e29\u5ea6\u7a0b\u5e8f\u662f\u5c06\u968f\u673a\u7684\u6e29\u5ea6\u8109\u51b2\u53e0\u52a0\u5728\u7ebf\u6027\u7684\u6e29\u5ea6\u7a0b\u5e8f\u4e0a\u3002\u5728<\/span>TOPEM\u5b9e\u9a8c\u4e2d\uff0c\u6e29\u5ea6\u8c03\u5236\u7684\u632f\u5e45\u4e3a\u5e38\u6570\uff0c\u4f46\u662f\u5728\u8c03\u5236\u51fd\u6570\u4e2d\u8109\u51b2\u7684\u6301\u7eed\u65f6\u95f4\u5728\u4e00\u4e2a\u8303\u56f4\u5185\u968f\u673a\u53d8\u5316\uff0c\u8fd9\u4e2a\u8303\u56f4\u53ef\u4ee5\u7531\u7528\u6237\u8bbe\u5b9a\u3002\u8303\u56f4\u7684\u8bbe\u5b9a\u662f\u901a\u8fc7\u9009\u62e9\u6700\u5c0f\u548c\u6700\u5927\u5207\u6362\u65f6\u95f4\u6765\u8fdb\u884c\u7684\u3002\u6d4b\u8bd5\u7ed3\u679c\u4e3a\u603b\u70ed\u6d41\u548c\u51c6\u7a33\u6001\u6bd4\u70ed\u5bb9<\/span>Cp0 \u3002\u7136\u540e\u7528\u6237\u53ef\u4ee5\u8ba1\u7b97\u4e0d\u540c\u9891\u7387\u4e0b\u7684\u6bd4\u70ed\u5bb9\u3002<\/span><\/span><\/p>\n <\/span><\/p>\n <\/span><\/p>\n \u56fe<\/span>2 TOPEM\u901a\u8fc7\u5bbd\u9891\u8303\u56f4\u6d4b\u8bd5\u4fe1\u53f7\uff0c\u968f\u673a\u6e29\u5ea6\u6270\u52a8<\/span><\/span><\/strong><\/p>\n <\/span><\/p>\n \u5728<\/span>TOPEM®\u4e2d\uff0c\u6570\u636e\u5206\u6790\u662f\u901a\u8fc7\u5bf9\u70ed\u6d41\u548c\u52a0\u70ed\u901f\u7387\u7684\u76f8\u5173\u6027\u5206\u6790\u6765\u8fdb\u884c\u7684\u3002\u8fd9\u5c31\u4ea7\u751f\u4e86\u4e0e\u52a0\u70ed\u901f\u7387\u76f8\u5173\u7684\u70ed\u6d41\u90e8\u5206\u548c\u4e0e\u52a0\u70ed\u901f\u7387\u4e0d\u76f8\u5173\u7684\u70ed\u6d41\u90e8\u5206\u3002\u4e0d\u76f8\u5173\u90e8\u5206\u5c31\u662f\u4e0d\u53ef\u9006\u70ed\u6d41<\/span>Φ<\/span>Non<\/span>\u3002\u53ef\u9006\u70ed\u6d41\u662f\u4ece\u76f8\u5173\u70ed\u6d41\u90e8\u5206\u5f97\u5230\u7684\u3002\u603b\u70ed\u6d41\u662f\u4e0d\u53ef\u9006\u70ed\u6d41\u548c\u53ef\u9006\u70ed\u6d41\u4e4b\u548c\u3002<\/span><\/span><\/p>\n <\/span><\/p>\n <\/span><\/p>\n <\/span><\/p>\n TOPEM\u6d4b\u8bd5\u8fc7\u7a0b\u662f\u51c6\u7a33\u6001\u6d4b\u8bd5\uff08\u5f53\u9891\u7387<\/span>\u03c9\u63a5\u8fd1<\/span>0\uff0c\u7c7b\u4f3c\u4e8e\u51c6\u7a33\u6001\uff09\uff0c\u5982\u679c\u7ebf\u6027\u548c\u7a33\u6001\u9700\u8981\u5728\u6d4b\u8bd5\u7cbe\u5ea6\u7684\u8303\u56f4\u5185\uff0c<\/span>TOPEM®\u6d4b\u8bd5\u7684\u53ef\u9006\u70ed\u6d41\u548c\u4e0d\u53ef\u9006\u70ed\u6d41\u53ef\u4ee5\u5f52\u5c5e\u4e3a\u663e\u70ed\u70ed\u6d41\u548c\u6f5c\u70ed\u70ed\u6d41\uff0c\u8fd9\u6837\u5c31\u80fd\u5206\u79bb\u663e\u70ed\u6d41\u548c\u6f5c\u70ed\u6d41\u3002<\/span><\/span><\/p>\n <\/span><\/p>\n TOPEM\u6280\u672f\u5e94\u7528\u793a\u4f8b<\/span><\/span><\/p>\n TOPEM\u6280\u672f\u9664\u4e86\u548c<\/span>ADSC\u4e00\u6837\u53ef\u4ee5\u5206\u79bb\u91cd\u53e0\u70ed\u6548\u5e94\u4e4b\u5916\uff0c\u8fd8\u53ef\u5f97\u5230\u51c6\u7a33\u6001\u6bd4\u70ed\u5bb9\uff1b\u5728\u4e00\u6b21\u5b9e\u9a8c\u5f97\u5230\u591a\u9891\u6570\u636e\uff0c\u5206\u6790\u9891\u7387\u4f9d\u8d56\u6027\uff1b\u66f4\u52a0\u9ad8\u51c6\u786e\u6027\u5206\u79bb\u663e\u70ed\u548c\u6f5c\u70ed\uff1b\u57fa\u4e8e\u51c6\u7a33\u6001\u70ed\u5bb9\u7684\u53ef\u9006\u70ed\u6d41\u4fe1\u53f7\u548c\u4e0d\u53ef\u9006\u70ed\u6d41\u4fe1\u53f7\u662f\u76f8\u5173\u6027\u5206\u6790\u7684\u76f4\u63a5\u7ed3\u679c\uff1b\u9002\u7528\u4e8e\u7814\u7a76\u56fa\u5316\u53cd\u5e94\u3001\u7ed3\u6676\u3001\u7194\u878d\u3001\u76f8\u8f6c\u53d8\u7b49\u3002<\/span><\/span><\/p>\n <\/span><\/p>\n \u56fe<\/span>3\u5c55\u793a\u4e86<\/span>PET\u8fdb\u884c<\/span>TOPEM\u6d4b\u8bd5\u7684\u66f2\u7ebf\uff0c\u7ecf\u8fc7\u5206\u6790\u53ef\u4ee5\u5f97\u5230\u603b\u70ed\u6d41\u66f2\u7ebf\uff0c\u53ef\u9006\u548c\u4e0d\u53ef\u9006\u70ed\u6d41\u66f2\u7ebf\u5206\u522b\u5bf9\u5e94\u4e8e\u663e\u70ed\u6d41\u548c\u6f5c\u70ed\u6d41\uff0c\u9891\u7387\u76f8\u5173\u6027\uff0c\u51c6\u7a33\u6001\u6bd4\u70ed\u5bb9\u3002\u5728\u8c03\u5236\u70ed\u6d41\u66f2\u7ebf\u4e2d\uff0c\u73bb\u7483\u5316\u8f6c\u53d8\u548c\u51b7\u6676\u5316\u90fd\u662f\u6e05\u6670\u53ef\u89c1\u7684\u3002\u53e6\u5916\u53ef\u4ee5\u770b\u5230\u5728<\/span>80\u2103\u5de6\u53f3\u7684\u73bb\u7483\u5316\u8f6c\u53d8\u8fc7\u7a0b\u4e2d\uff0c\u70ed\u5bb9\u589e\u52a0\uff0c\u4f46\u5728\u51b7\u7ed3\u6676\u65f6\u53c8\u7565\u6709\u964d\u4f4e\uff0c\u8fd9\u79cd\u884c\u4e3a\u5728\u76f8\u4f4d\u66f2\u7ebf\u4e2d\u66f4\u52a0\u660e\u663e\u3002\u9664\u4e86\u51c6\u9759\u6001\u66f2\u7ebf\u5916\uff0c\u56fe\u4e2d\u8fd8\u663e\u793a\u4e86\u6d4b\u91cf\u9891\u7387\u4e3a<\/span>16.7 Hz\u65f6\u7684\u66f2\u7ebf\u3002\u5728\u73bb\u7483\u5316\u8f6c\u53d8\u65f6\uff0c\u968f\u7740\u9891\u7387\u7684\u589e\u52a0\uff0c\u6e29\u5ea6\u5411\u66f4\u9ad8\u6e29\u5ea6\u7684\u8f6c\u53d8\u53ef\u4ee5\u6e05\u695a\u5730\u770b\u5230\u3002\u76f8\u53cd\uff0c\u5728\u51b7\u7ed3\u6676\u65f6\uff0c\u6ca1\u6709\u89c2\u5bdf\u5230\u4f4d\u79fb\uff0c\u8bf4\u660e\u8fd9\u79cd\u6548\u5e94\u53ea\u53d6\u51b3\u4e8e\u6e29\u5ea6\uff0c\u53ef\u4ee5\u5728\u4e00\u6b21\u5b9e\u9a8c\u6d4b\u8bd5\u4e2d\u7814\u7a76\u9891\u7387\u7684\u4f9d\u8d56\u6027\u3002<\/span><\/span><\/p>\n <\/span><\/p>\n <\/span><\/p>\n \u56fe<\/span>3 PET\u6750\u6599\u7684<\/span>TOPEM\u8c03\u5236\u5206\u6790\u66f2\u7ebf<\/span><\/span><\/strong><\/p>\n <\/span><\/p>\n \u7ed3\u8bba<\/span><\/strong><\/p>\n TOPEM\u662f\u6885\u7279\u52d2\u6258\u5229\u591a\u5f00\u53d1\u7684\u591a\u9891\u968f\u673a\u6e29\u5ea6\u8c03\u5236<\/span>DSC\u6280\u672f\uff0c\u8fd9\u79cd\u6280\u672f\u4f7f\u6f5c\u70ed\u548c\u663e\u70ed\u5206\u79bb\u6210\u4e3a\u53ef\u80fd\uff0c\u5728\u8db3\u591f\u4f4e\u7684\u57fa\u7840\u52a0\u70ed\u901f\u7387\u548c\u5c0f\u7684\u6e29\u5ea6\u5fae\u6270\u4e0b\uff0c\u5373\u6ee1\u8db3\u7ebf\u6027\u548c\u7a33\u6001\u7684\u6761\u4ef6\u4e0b\uff0c\u4f5c\u4e3a\u7ed3\u679c\u5f97\u5230\u7684\u53ef\u9006\u70ed\u6d41\u548c\u4e0d\u53ef\u9006\u70ed\u6d41\u4e0e\u8be5\u57fa\u7840\u52a0\u70ed\u901f\u7387\u4e0b\u7684\u663e\u70ed\u6d41\u548c\u6f5c\u70ed\u6d41\u5206\u91cf\u76f8\u7b49\uff0c\u5373<\/span>ΦRev=ΦSen\u548c<\/span>ΦNon=ΦLat\uff0c\u5e76\u5177\u6709\u8f83\u9ad8\u7684\u7cbe\u786e\u5ea6\u3002\u9891\u7387\u8bc4\u4f30\u8fd8\u5141\u8bb8\u901a\u8fc7\u4e00\u6b21\u6d4b\u91cf\u5728\u8f83\u5bbd\u7684\u9891\u7387\u8303\u56f4\u5185\u786e\u5b9a\u590d\u6742\u7684<\/span>(\u9891\u7387\u76f8\u5173\u7684<\/span>)\u70ed\u5bb9\uff0c\u6240\u83b7\u5f97\u7684\u4fe1\u606f\u52a9\u529b\u4e8e\u89e3\u91ca\u70ed\u4e8b\u4ef6\u4ee5\u53ca\u8fc7\u7a0b\u52a8\u529b\u5b66\u7684\u7814\u7a76\u3002<\/span><\/span><\/strong><\/p>\n <\/span><\/p>\n \u53c2\u8003\u6587\u732e<\/span><\/span><\/strong><\/p>\n [1] M. Reading. Trends Polym. Sci. 1 (1993) 248.<\/span><\/p>\n [2] J.E.K. Schawe. Thermochim Acta 260 (1995) .<\/span><\/p>\n [3] \u9646\u7acb\u660e<\/span>, \u968f\u673a\u6e29\u5ea6\u8c03\u5236<\/span>DSC\u6280\u672f<\/span>TOPEM\u7684\u7406\u8bba\u548c\u5e94\u7528<\/span>.<\/span><\/p>\n [4] J. Schawe, UserCom 20, 11.<\/span><\/p>\n [5] J. Schawe, UserCom 22, 11.<\/span><\/p>\n <\/p>\n<\/p><\/div>\n<\/p><\/div>\n","protected":false},"excerpt":{"rendered":" [db:\u6458\u8981]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[4],"tags":[5],"_links":{"self":[{"href":"http:\/\/www.gongyeqx.com\/index.php?rest_route=\/wp\/v2\/posts\/2506"}],"collection":[{"href":"http:\/\/www.gongyeqx.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.gongyeqx.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.gongyeqx.com\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/www.gongyeqx.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=2506"}],"version-history":[{"count":1,"href":"http:\/\/www.gongyeqx.com\/index.php?rest_route=\/wp\/v2\/posts\/2506\/revisions"}],"predecessor-version":[{"id":2677,"href":"http:\/\/www.gongyeqx.com\/index.php?rest_route=\/wp\/v2\/posts\/2506\/revisions\/2677"}],"wp:attachment":[{"href":"http:\/\/www.gongyeqx.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=2506"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.gongyeqx.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=2506"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.gongyeqx.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=2506"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}